Potentiometric diclofenac detection in wastewater using functionalized nanoparticles

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dc.AffiliationOctober University for modern sciences and Arts (MSA)
dc.contributor.authorElbalkiny H.T.
dc.contributor.authorYehia A.M.
dc.contributor.authorRiad S.M.
dc.contributor.authorElsaharty Y.S.
dc.contributor.otherAnalytical Chemistry Department
dc.contributor.otherFaculty of Pharmacy
dc.contributor.otherOctober University for Modern Sciences and Arts (MSA)
dc.contributor.other6th October City
dc.contributor.other11787
dc.contributor.otherEgypt; Analytical Chemistry Department
dc.contributor.otherFaculty of Pharmacy
dc.contributor.otherCairo University
dc.contributor.otherKasr-El Aini 13 Street
dc.contributor.otherCairo
dc.contributor.other11562
dc.contributor.otherEgypt; Chemistry Department
dc.contributor.otherSchool of Pharmacy and Pharmaceutical Industries
dc.contributor.otherBadr University in Cairo
dc.contributor.otherBadr City
dc.contributor.otherCairo
dc.contributor.other11829
dc.contributor.otherEgypt
dc.date.accessioned2020-01-09T20:40:40Z
dc.date.available2020-01-09T20:40:40Z
dc.date.issued2019
dc.descriptionScopus
dc.description.abstractIon selective electrodes for diclofenac monitoring in both pharmaceutical wastewater and dosage form were described; that are considered environmental friendly analytical method. The sensors development depended on comparative performance evaluation of membranes that were based on functionalized magnetite nanoparticles with the classical sensors; this approach provided that nanoparticles in the inner solution of sensor membrane were highly dispersed and coated with ionophore to enhance a complete ion-pairing interaction between the ionophore and the analyte. The optimum membrane was that containing ??cyclodextrin coupled with magnetite ferric oxide as inner filling solution, dibutylphthalate as plasticizer and crystal violet as ion exchanger in poly (vinylchloride) matrix. This sensor (CV-Fe-?-CD) exhibited high sensitivity, Nernstian slope of the calibration curve, as well as fast, stable response and good selectivity. The sensor exhibits a Nernstian slope of ?58.7 � 1 mV/decade over the concentration range 1.0 � 10?7 to 1.0 � 10?2 M of Diclofenac with a minimal limit of detection of 1.1 � 10?7 M. The electrode showed a good potentiometric selectivity for diclofenac with respect to a number of interfering ions and organic species. The membrane sensor was successfully applied for the determination of diclofenac in wastewater samples and dosage form without sample pretreatment steps prior to its analysis. � 2018 Elsevier B.V.en_US
dc.description.urihttps://www.scimagojr.com/journalsearch.php?q=20922&tip=sid&clean=0
dc.identifier.doihttps://doi.org/10.1016/j.microc.2018.10.017
dc.identifier.doiPubMed ID :
dc.identifier.issn0026265X
dc.identifier.otherhttps://doi.org/10.1016/j.microc.2018.10.017
dc.identifier.otherPubMed ID :
dc.identifier.urihttps://t.ly/ve8KW
dc.language.isoEnglishen_US
dc.publisherElsevier Inc.en_US
dc.relation.ispartofseriesMicrochemical Journal
dc.relation.ispartofseries145
dc.subjectDiclofenacen_US
dc.subjectIon selective electrodeen_US
dc.subjectMagnetite nanoparticlesen_US
dc.subjectWastewateren_US
dc.titlePotentiometric diclofenac detection in wastewater using functionalized nanoparticlesen_US
dc.typeArticleen_US
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