Electrochemical behavior of Al 2 O 3 /Al composite coated Al electrodes through surface mechanical alloying in alkaline media
Date
2019
Authors
Journal Title
Journal ISSN
Volume Title
Type
Article
Publisher
International Journal of Pharmacognosy and Phytochemical Research
Elsevier B.V.
Elsevier B.V.
Series Info
Current Applied Physics
19
19
Scientific Journal Rankings
Abstract
The behavior of Al 2 O 3 /Al composite coated Al electrodes fabricated by surface mechanical alloying 'sMA� was studied. The work was accomplished using Cyclic voltammetry and electrochemical impedance spectroscopy (EIS) techniques in alkaline media 2MKOH were done at room temperature. Results show hydroxyl ions accumulate on the surface due to Al deformation micro cavities filling with Al 2 O 3 until full charge blockage reached. A barrier cover layer development causing an increase of both resistance and capacitance as it becomes more stable and thinner with exposure time increase. Migrating hydroxyl ion inside micro cavity changed its composition from Al 2 O 3 to stable tetrahedral Al(OH) 4 ? aluminate ions. Therefore future benefits could be reached by developing such surfaces having charge accumulation that enables environmental interaction. � 2019 Korean Physical Society
Description
Scopus
Keywords
October University for Modern Sciences and Arts, جامعة أكتوبر للعلوم الحديثة والآداب, University of Modern Sciences and Arts, MSA University, Cyclic voltammetry, Electrochemical impedance spectroscopy, Surface composites, Surface mechanical alloying, Alumina, Aluminum coatings, Aluminum oxide, Cyclic voltammetry, Electrochemical impedance spectroscopy, Ions, Mechanical alloying, Microcavities, Sodium Aluminate, Spectroscopy, Alkaline media, Aluminate ions, Charge accumulation, Electrochemical behaviors, Environmental interactions, Exposure-time, Future benefits, Surface composites, Electrochemical electrodes