Ion-Selective membrane sensors for the determination of ciprofloxacin hydrochloride in water and pharmaceutical formulation

dc.AffiliationOctober University for modern sciences and Arts (MSA)
dc.contributor.authorRiad S.M.
dc.contributor.authorKhattab F.I.
dc.contributor.authorSalem H.
dc.contributor.authorElbalkiny H.T.
dc.contributor.otherAnalytical Chemistry Department
dc.contributor.otherCairo University
dc.contributor.otherKasr-El Aini Street
dc.contributor.otherCairo
dc.contributor.other11562
dc.contributor.otherEgypt; Analytical Chemistry Department
dc.contributor.otherOctober University for Modern Sciences and Arts (MSA)
dc.contributor.other6th October City
dc.contributor.other11787
dc.contributor.otherEgypt
dc.date.accessioned2020-01-09T20:42:12Z
dc.date.available2020-01-09T20:42:12Z
dc.date.issued2014
dc.descriptionScopus
dc.description.abstractThe construction and electrochemical response characteristics of six Ciprofloxacin-selective electrodes were investigated using precipitation based technique with sodium tetraphenyl borate (TPB), phosphomolybdate (PMA) and phosphotungstate (PTA); respectively upon using polyvinyl chloride (PVC) matrix and dibutyl phthalate (DBP) as a plasticizer. The resultant sensors have different forms, either as membrane electrodes (sensors 1, 3 and 5) or as coated wire electrodes (sensors 2, 4 and 6). Linear responses of CIP within the concentration ranges of 10?6 to 10?2 mol/L for sensors 1, 2 and 5 while for sensors 3 and 4, the linear responses were within the concentration ranges of 10?5 to 10?2 mol/L and for sensor 6 it shows linear responses within the concentration ranges of 10?7 to 10?2 mol/L. Nernstian slopes of 51.7, 50.7, 58.3, 57.7, 44 and 41.8 mV/decade were observed over the pH range of (5�9) for sensors 1, 2, 5 and 6 and over range of (5-7) for sensor 3 and 4 respectively. The selectivity coefficients of the developed sensors indicated excellent selectivity for CIP. The proposed sensors displayed useful analytical characteristics for the determination of CIP in water samples and pharmaceutical preparation. 2014 by CEE.en_US
dc.description.urihttps://www.scimagojr.com/journalsearch.php?q=21100224440&tip=sid&clean=0
dc.identifier.doihttps://doi.org/
dc.identifier.issn20084226
dc.identifier.otherhttps://doi.org/
dc.identifier.urihttps://t.ly/0Bmzj
dc.language.isoEnglishen_US
dc.publisherCenter of Excellence in Electrochemistry, Univ. of Tehranen_US
dc.relation.ispartofseriesAnalytical and Bioanalytical Electrochemistry
dc.relation.ispartofseries6
dc.subjectCiprofloxacin HClen_US
dc.subjectPhosphomolybdic aciden_US
dc.subjectPhosphotungestic aciden_US
dc.subjectTetraphenyl borateen_US
dc.subjectWater samplesen_US
dc.titleIon-Selective membrane sensors for the determination of ciprofloxacin hydrochloride in water and pharmaceutical formulationen_US
dc.typeArticleen_US
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