Reactivity ratios during radiation-induced grafting of comonomer mixtures onto polyester fabrics
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Date
2001
Authors
Journal Title
Journal ISSN
Volume Title
Type
Article
Publisher
JOHN WILEY & SONS LTD
Series Info
POLYMER INTERNATIONAL;Volume: 50 Issue: 10 Pages: 1082-1088
Scientific Journal Rankings
Abstract
Radiation-induced grafting of binary mixtures of acrylonitrile (AN)/styrene (S) and acrylamide (AAm)/styrene (S) onto polyester fabric (PET) has been investigated. Synergism during radiation grafting was investigated by determining the graft yield fraction for each monomer in the final graft copolymer. Moreover, by knowing the mole fraction of each monomer in the grafting solution, the reactivity ratio of the individual monomers in the comonomer mixture during graft copolymerization could be determined: in the case of AN/S comonomer mixture, the calculated reactivity ratios for AN and S are 0.04 and 0.05, respectively; the calculated reactivity ratios of AAm and S in their comonomer mixture are 1.82 and 0.41, respectively. (C) 2001 Society of Chemical Industry.
Description
Accession Number: WOS:000171435700004
Keywords
reactivity ratios, mixed monomers, radiation grafting, polyester fabrics, VINYL MONOMERS, BINARY-MIXTURES, MIXED MONOMERS, POLYPROPYLENE, COPOLYMERIZATION
Citation
Cited References in Web of Science Core Collection: 11