Derivative constant wavelength synchronous fluorescence spectrometry for the simultaneous detection of cefadrine and cefadroxil in water samples

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dc.AffiliationOctober University for modern sciences and Arts (MSA)
dc.contributor.authorElbalkiny H.T.
dc.contributor.authorYehia A.M.
dc.contributor.authorRiad S.M.
dc.contributor.authorElsaharty Y.S.
dc.contributor.otherAnalytical Chemistry Department
dc.contributor.otherFaculty of Pharmacy
dc.contributor.otherOctober University for Modern Sciences and Arts (MSA)
dc.contributor.other6th October City
dc.contributor.other11787
dc.contributor.otherEgypt; Analytical Chemistry Department
dc.contributor.otherFaculty of Pharmacy
dc.contributor.otherCairo University
dc.contributor.otherKasr-El Aini 13 Street
dc.contributor.otherCairo
dc.contributor.other11562
dc.contributor.otherEgypt; Chemistry Department
dc.contributor.otherSchool of Pharmacy and Pharmaceutical Industries
dc.contributor.otherBadr University in Cairo
dc.contributor.otherBadr City
dc.contributor.otherCairo 11829
dc.contributor.otherEgypt
dc.date.accessioned2020-01-09T20:40:28Z
dc.date.available2020-01-09T20:40:28Z
dc.date.issued2020
dc.descriptionScopus
dc.description.abstractA sensitive accurate spectrofluorimetric technique was developed to detect cefadroxil and cefradine traces in water samples simultaneously, by applying a procedure based on the formation of hydrolysis products corresponding to these compounds by sodium hydroxide (1 N NaOH) treatment. The conventional and the synchronous fluorescence spectra of these hydrolyzed products were totally overlapped making resolving of this mixture impossible. The second-derivative constant-wavelength synchronous fluorescence spectra allowed their detection simultaneously in a single scan after experimental conditions optimization, which was measured at 390 nm and 379 nm for cefadroxil and cefradine, respectively at ?? = 30.0. The calibration curves between derivative synchronous fluorescence intensity and drugs concentration showed suitable linear correlation in the range of 0.1 to 5 ?g.mL? 1 for cefadroxil and 0.5�10 ?g.mL? 1 for cefradine. The proposed fluorimetric method is superior in being simple, environmental friendly and cost effective in comparison to the previously published reported methods. � 2019 Elsevier B.V.en_US
dc.description.urihttps://www.scimagojr.com/journalsearch.php?q=24530&tip=sid&clean=0
dc.identifier.doihttps://doi.org/10.1016/j.saa.2019.117903
dc.identifier.doiPubMed ID :
dc.identifier.issn13861425
dc.identifier.otherhttps://doi.org/10.1016/j.saa.2019.117903
dc.identifier.otherPubMed ID :
dc.identifier.urihttps://t.ly/veGEb
dc.language.isoEnglishen_US
dc.publisherElsevier B.V.en_US
dc.relation.ispartofseriesSpectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
dc.relation.ispartofseries229
dc.subjectCefadroxilen_US
dc.subjectCefradine and water samplesen_US
dc.subjectDerivative synchronous spectrofluorimetryen_US
dc.subjectCost effectivenessen_US
dc.subjectFluorescence spectroscopyen_US
dc.subjectHydrolysisen_US
dc.subjectSodium hydroxideen_US
dc.subjectCefadroxilen_US
dc.subjectEnvironmental-friendlyen_US
dc.subjectExperimental conditionsen_US
dc.subjectHydrolysis productsen_US
dc.subjectSimultaneous detectionen_US
dc.subjectSpectrofluorimetryen_US
dc.subjectSynchronous fluorescenceen_US
dc.subjectWater samplesen_US
dc.subjectFluorescenceen_US
dc.titleDerivative constant wavelength synchronous fluorescence spectrometry for the simultaneous detection of cefadrine and cefadroxil in water samplesen_US
dc.typeArticleen_US
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