Monitoring and optimization of diclofenac removal by adsorption technique using in-line potentiometric analyzer

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dc.AffiliationOctober University for modern sciences and Arts (MSA)
dc.contributor.authorYehia A.M.
dc.contributor.authorElbalkiny H.T.
dc.contributor.authorRiad S.M.
dc.contributor.authorElsaharty Y.S.
dc.contributor.otherAnalytical Chemistry Department
dc.contributor.otherFaculty of Pharmacy
dc.contributor.otherCairo University
dc.contributor.otherKasr-El Aini 13 Street
dc.contributor.otherCairo
dc.contributor.other11562
dc.contributor.otherEgypt; Chemistry Department
dc.contributor.otherSchool of Pharmacy and Pharmaceutical Industries
dc.contributor.otherBadr University in Cairo
dc.contributor.otherBadr City
dc.contributor.otherCairo 11829
dc.contributor.otherEgypt; Analytical Chemistry Department
dc.contributor.otherFaculty of Pharmacy
dc.contributor.otherOctober University for Modern Sciences and Arts (MSA)
dc.contributor.other6th October City
dc.contributor.other11787
dc.contributor.otherEgypt
dc.date.accessioned2020-01-09T20:40:36Z
dc.date.available2020-01-09T20:40:36Z
dc.date.issued2019
dc.descriptionScopus
dc.description.abstractDiclofenac (DICLO) is one of the most prescribed non-steroidal anti-inflammatory drugs worldwide. The presence of DICLO residues in aquatic environment either from industrial or hospital wastewater has harmful effects on many organisms. In this contribution, the adsorption of DICLO on granulated active carbon and mesoporous silica nanoparticles was optimized in order to remove those residues from water. The tracking of DICLO was done using in-line potentiometric ion-selective electrodes (ISE) through the whole experiments. The constructed electrode allows tracking of DICLO residues in real time. A central composite design was applied, inspecting the pH, initial concentration, adsorbent loading concentration and adsorbent type effects on the adsorption process, the results showed that the pH effect was most significant; pH 5 gave best results. The adsorption kinetics of these adsorbents have been investigated and the results indicated that the adsorption process followed the pseudo-second-order kinetic model. The adsorption isotherm data were analyzed by both Langmuir and Freundlich models and later provides better fit of the experimental data. The removal efficiency was about ~89% upon applying the optimum set of experimental conditions in time < 60 min. In-line monitoring is considered a green protocol, that should be carried out also at the pharmaceutical industry scale due to the high selectivity, lack of harmful waste generation and minimal solvent use. � 2019 Elsevier B.V.en_US
dc.description.urihttps://www.scimagojr.com/journalsearch.php?q=20922&tip=sid&clean=0
dc.identifier.doihttps://doi.org/10.1016/j.microc.2019.05.005
dc.identifier.doiPubMed ID :
dc.identifier.issn0026265X
dc.identifier.otherhttps://doi.org/10.1016/j.microc.2019.05.005
dc.identifier.otherPubMed ID :
dc.identifier.urihttps://t.ly/NXNZK
dc.language.isoEnglishen_US
dc.publisherElsevier Inc.en_US
dc.relation.ispartofseriesMicrochemical Journal
dc.relation.ispartofseries148
dc.subjectAdsorptionen_US
dc.subjectCentral composite designen_US
dc.subjectDiclofenacen_US
dc.subjectGranulated active charcoalen_US
dc.subjectIon selective electrodeen_US
dc.subjectMesoporous silica nanoparticlesen_US
dc.subjectWastewater treatmenten_US
dc.titleMonitoring and optimization of diclofenac removal by adsorption technique using in-line potentiometric analyzeren_US
dc.typeArticleen_US
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