Crispy Dry Chili Extract as an Eco‑Friendly Corrosion Inhibitor for Mild Steel in Chloride Solutions: Experimental and Theoretical Studies
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Date
2022-12
Journal Title
Journal ISSN
Volume Title
Type
Article
Publisher
Springer International Publishing AG
Series Info
Journal of Bio- and Tribo-Corrosion;Volume 8, Issue 4December 2022 Article number 97
Scientific Journal Rankings
Abstract
The development of eco-friendly corrosion inhibitors is an area under several investigations; especially, natural plant extract.
Such as crispy dry capsicum chili extracts (containing capsaicinoids as the active ingredient), the plant extract is an inex-
pensive and renewable material. Surface properties were studied such as fourier transforms infrared spectroscopy, contact
angle measurements (θ), and scanning electron microscope. The inhibitive efects of the extract on mild steel in chloride
solutions were experimentally evaluated by electrochemical methods such as potentiodynamic polarization, and electro-
chemical impedance spectroscopy. The results illustrated that the maximum inhibition efciency of the coating was 97.1,
94.7, and 85.2%, for mild steel in 3.5% NaCl, 2.0, and 1.0 M HCl, respectively. The protective hydrophobic flm attributed
high protection to the homogeneous distribution. The signifcance of quantum chemical descriptors to the performance of the
extract as a corrosion inhibitor was determined using the density functional theory. Quantum parameters were evaluated and
discussed, such as the highest and lowest occupied orbital energy, the energy gap, hardness, and other quantum descriptors.
Description
Scopus
Keywords
Plant extract , Eco-friendly corrosion inhibitor , PDP , Contact angle , DFT