Physical and mechanical evaluation of dental resin composite after modification with two different types of Montmorillonite nanoclay

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Date

6/27/2021

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Journal ISSN

Volume Title

Type

Article

Publisher

Elsevier

Series Info

Journal of Dentistry;Volume 112September 2021 Article number 103731

Abstract

Objectives: Evaluation of degree of conversion (DC), flexural properties, micro-hardness and color change (ΔE00) of dental resin composite after modification with two types of organo-modified Montmorillonite (MMT) nano- clay; an experimentally synthesized polymethyl-methacrylate modified MMT nanoclay (PMMA/MMT), and a commercially available one (Cloisite20A). Methods: MMT was synthesized by sol-gel technique, organo-modified with polymethyl-methacrylate and char- acterized using EDX, XRD and FTIR. PMMA/MMT and Cloisite20A nanoclay were added to flowable resin composite in 0.5, 1 and 1.5 wt% concentrations. Unmodified resin composite was used as control group. DC was assessed by FTIR, flexural properties were tested by three-point bending test using a universal testing machine, micro-hardness was analyzed by Vickers micro-hardness tester and color change (ΔE00) was evaluated using a reflective spectrophotometer. SEM and elemental mapping assessment were performed to evaluate nanoclay distribution in resin composite. Data were analyzed using One-way ANOVA followed by Tukey’s post hoc test, in addition to Two-way ANOVA (p ≤ 0.05). Weibull analysis was used to analyze flexural strength results. Results: Characterization results revealed successful preparation of PMMA/MMT. DC results showed insignificant difference up to 1 wt% of nanoclay concentration. Addition of 0.5 wt% of PMMA/MMT significantly increased flexural properties, while addition of 1.5 wt% of PMMA/MMT significantly decreased flexural properties. Micro- hardness results revealed a significant increase in PMMA/MMT groups in all tested concentrations. ΔE00 results showed that color change was clinically acceptable on adding 0.5 wt% nanoclay. Conclusion: PMMA/MMT in 0.5 wt% is a promising nanofiller for resin composite that significantly enhanced flexural strength and micro-hardness without compromising DC and color.

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Keywords

Resin composite, Nanoclay, Montmorillonite, Nanofillers, Dental materials, Weibull Analysis

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