Field-amplified sample stacking cyclodextrin modified capillary electrophoresis for quantitative determination of diastereomeric saponins

Emara S.; Masujima T.; Zarad W.; Mohamed K.; Kamal M.; Fouad M.; EL-Bagary R.

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dc.contributor.author	Emara S.
dc.contributor.author	Masujima T.
dc.contributor.author	Zarad W.
dc.contributor.author	Mohamed K.
dc.contributor.author	Kamal M.
dc.contributor.author	Fouad M.
dc.contributor.author	EL-Bagary R.
dc.contributor.other	Faculty of Pharmacy
dc.contributor.other	Pharmaceutical Chemistry Department
dc.contributor.other	Misr International University
dc.contributor.other	Km 28 Ismailia Road
dc.contributor.other	Cairo
dc.contributor.other	Egypt; P.I. Laboratory Single Cell MS
dc.contributor.other	RIKEN Quantitative Biology Center
dc.contributor.other	6-2-3
dc.contributor.other	Furuedai
dc.contributor.other	Suita
dc.contributor.other	Osaka
dc.contributor.other	565-0874
dc.contributor.other	Japan; Faculty of Pharmacy
dc.contributor.other	Pharmacognosy Department
dc.contributor.other	Assiut University
dc.contributor.other	Assiut
dc.contributor.other	71526
dc.contributor.other	Egypt; Faculty of Pharmacy
dc.contributor.other	Pharmaceutical Analytical Chemistry Department
dc.contributor.other	Modern Sciences and Arts University
dc.contributor.other	26 July Mehwar Road Intersection with Wahat Road
dc.contributor.other	6 October City
dc.contributor.other	Egypt; Faculty of Pharmacy
dc.contributor.other	Pharmaceutical Chemistry Department
dc.contributor.other	Cairo University
dc.contributor.other	Kasr El Aini St.
dc.contributor.other	Cairo
dc.contributor.other	11562
dc.contributor.other	Egypt
dc.date.accessioned	2020-01-09T20:42:19Z
dc.date.available	2020-01-09T20:42:19Z
dc.date.issued	2014
dc.identifier.issn	219665
dc.identifier.other	https://doi.org/10.1093/chromsci/bmt169
dc.identifier.other	PubMed ID 24248558
dc.identifier.uri	https://t.ly/lWOED
dc.description	Scopus
dc.description.abstract	Successful simultaneous diastereomeric separation and sensitive determination of two pairs of triterpenoidal saponins have been achieved by capillary electrophoresis (CE) using ?-cyclodextrin (?-CD) as a stereoselective agent to cooperate with borate complexation. A usual technique for isolation and group separation of saponins was developed as an appropriate purification step prior to the determination of individual saponins by CE. Soyasaponin I (S1), azukisaponin V (S2), bersimoside I (S3) and bersimoside II (S4) could be well separated within 14 min in a fused-silica capillary (60 cm long to the detector with an additional 10 cm to the cathode; 75 ?m i.d.). The background electrolyte was borate buffer (80 mM, pH 10), containing 24 mM ?-CD. The separation voltage was 14 kV with a detection wavelength of 195 nm. The sample was electrokinetically injected using a voltage of 16 kV for 12 s. Methanol (70%) was used as the diluent for field-amplified sample stacking after hydrodynamic injection of short water plug (5 cm, 4 s). The method was partially validated for linearity, repeatability, reproducibility, limits of detection and limits of quantification. The correlation coefficients of the calibration curves were all >0.998, and the recoveries were from 98.23 to 96.21%. The Author [2013]. Published by Oxford University Press. All rights reserved.	en_US
dc.description.uri	https://www.scimagojr.com/journalsearch.php?q=24023&tip=sid&clean=0
dc.language.iso	English	en_US
dc.publisher	Springer Netherlands
dc.publisher	Oxford University Press	en_US
dc.relation.ispartofseries	Journal of Chromatographic Science
dc.relation.ispartofseries	52
dc.subject	October University for Modern Sciences and Arts
dc.subject	جامعة أكتوبر للعلوم الحديثة والآداب
dc.subject	University of Modern Sciences and Arts
dc.subject	MSA University
dc.subject	beta cyclodextrin derivative	en_US
dc.subject	boric acid	en_US
dc.subject	plant extract	en_US
dc.subject	saponin	en_US
dc.subject	capillary electrophoresis	en_US
dc.subject	chemistry	en_US
dc.subject	clover	en_US
dc.subject	limit of detection	en_US
dc.subject	pH	en_US
dc.subject	plant seed	en_US
dc.subject	procedures	en_US
dc.subject	reproducibility	en_US
dc.subject	statistical model	en_US
dc.subject	beta-Cyclodextrins	en_US
dc.subject	Borates	en_US
dc.subject	Electrophoresis, Capillary	en_US
dc.subject	Hydrogen-Ion Concentration	en_US
dc.subject	Limit of Detection	en_US
dc.subject	Linear Models	en_US
dc.subject	Plant Extracts	en_US
dc.subject	Reproducibility of Results	en_US
dc.subject	Saponins	en_US
dc.subject	Seeds	en_US
dc.subject	Trifolium	en_US
dc.title	Field-amplified sample stacking cyclodextrin modified capillary electrophoresis for quantitative determination of diastereomeric saponins	en_US
dc.type	Article	en_US
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dcterms.source	Scopus
dc.identifier.doi	https://doi.org/10.1093/chromsci/bmt169
dc.identifier.doi	PubMed ID 24248558
dc.Affiliation	October University for modern sciences and Arts (MSA)