Ion-Selective membrane sensors for the determination of ciprofloxacin hydrochloride in water and pharmaceutical formulation

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dc.contributor.author Riad S.M.
dc.contributor.author Khattab F.I.
dc.contributor.author Salem H.
dc.contributor.author Elbalkiny H.T.
dc.contributor.other Analytical Chemistry Department
dc.contributor.other Cairo University
dc.contributor.other Kasr-El Aini Street
dc.contributor.other Cairo
dc.contributor.other 11562
dc.contributor.other Egypt; Analytical Chemistry Department
dc.contributor.other October University for Modern Sciences and Arts (MSA)
dc.contributor.other 6th October City
dc.contributor.other 11787
dc.contributor.other Egypt
dc.date.accessioned 2020-01-09T20:42:12Z
dc.date.available 2020-01-09T20:42:12Z
dc.date.issued 2014
dc.identifier.issn 20084226
dc.identifier.other https://doi.org/
dc.identifier.uri https://t.ly/0Bmzj
dc.description Scopus
dc.description.abstract The construction and electrochemical response characteristics of six Ciprofloxacin-selective electrodes were investigated using precipitation based technique with sodium tetraphenyl borate (TPB), phosphomolybdate (PMA) and phosphotungstate (PTA); respectively upon using polyvinyl chloride (PVC) matrix and dibutyl phthalate (DBP) as a plasticizer. The resultant sensors have different forms, either as membrane electrodes (sensors 1, 3 and 5) or as coated wire electrodes (sensors 2, 4 and 6). Linear responses of CIP within the concentration ranges of 10?6 to 10?2 mol/L for sensors 1, 2 and 5 while for sensors 3 and 4, the linear responses were within the concentration ranges of 10?5 to 10?2 mol/L and for sensor 6 it shows linear responses within the concentration ranges of 10?7 to 10?2 mol/L. Nernstian slopes of 51.7, 50.7, 58.3, 57.7, 44 and 41.8 mV/decade were observed over the pH range of (5�9) for sensors 1, 2, 5 and 6 and over range of (5-7) for sensor 3 and 4 respectively. The selectivity coefficients of the developed sensors indicated excellent selectivity for CIP. The proposed sensors displayed useful analytical characteristics for the determination of CIP in water samples and pharmaceutical preparation. 2014 by CEE. en_US
dc.description.uri https://www.scimagojr.com/journalsearch.php?q=21100224440&tip=sid&clean=0
dc.language.iso English en_US
dc.publisher Center of Excellence in Electrochemistry, Univ. of Tehran en_US
dc.relation.ispartofseries Analytical and Bioanalytical Electrochemistry
dc.relation.ispartofseries 6
dc.subject Ciprofloxacin HCl en_US
dc.subject Phosphomolybdic acid en_US
dc.subject Phosphotungestic acid en_US
dc.subject Tetraphenyl borate en_US
dc.subject Water samples en_US
dc.title Ion-Selective membrane sensors for the determination of ciprofloxacin hydrochloride in water and pharmaceutical formulation en_US
dc.type Article en_US
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dcterms.source Scopus
dc.identifier.doi https://doi.org/
dc.Affiliation October University for modern sciences and Arts (MSA)


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