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The new colorant succeeded in printing silk, wool, cotton, polyester, and nylon as well as their different blends in the presence and absence of binder. Prints of the new colorant were compared with those obtained using commercial pigment. The effect of adding different amounts of binder to the printing paste on major technical properties of the prints was also investigated. Evaluation of the various printed fabrics was performed through monitoring color strength (K/S), TEM images, SEM micrographs, and overall fastness properties.en-USACIDSYSTEMSULFURADSORPTIONFUNCTIONALIZATIONREDUCTIONNANOPARTICLESCOTTONAQUEOUS-SOLUTIONVAT DYESBinder and various fabricsPigmentMontmorillonite (MMT)New hybrid nanocompositeIndigo blue vat dyeArticlehttps://doi.org/10.1007/s12221-019-7809-3